A lithium superionic conductor pdf

Design principles for solidstate lithium superionic. It also suffers from high interfacial resistances with the electrodes. Herein, we report a novel sodium superionic conductor with nasicon structure, na3. It exhibits an extremely high lithium ionic conductivity of 12 ms cm. Through firstprinciples calculations and crystal structure prediction techniques, we identify a new layered oxysulfide lialso in orthorhombic structure as a novel lithium superionic conductor. Practical challenges and future perspectives of allsolidstate lithiummetal batteries shuixin xia, 1,4xinsheng wu. Xuelong wang,1,2 ruijuan xiao,1, hong li,1 and liquan chen1. A lithium superionic conductor from first principles xuelong wang,1,2 ruijuan xiao,1, hong li,1 and liquan chen1 1beijing national laboratory for condensed matterphysics, institute ofphysics, chineseacademy of sciences, beijing 100190,china 2university of chinese academy of sciences, beijing 49, china received 23 january 2017. Among these solid electrolytes, the crystalline lithium superionic conductors have been paid much attention due to their high li ionic conductivity. The nanoporous lps is a superionic conductor offering good electrochemical stability and favorable ionic conductivity. Superionic conductivity in a lithium aluminum germanium. A lithium superionic conductor as a new solidstate. Presented are new, earthabundant lithium superionic conductors, li 3 yps 4 2 and ll 5 ps 4 ci 2, that emerged from a comprehensive screening of the lips and limps chemical spaces.

The rigid ion sublattice of adsics have structure channels where mobile ions of opposite sign. The empty space in between these polyanion groups hosts li ions as li sites and forms interconnected channels. New family of argyrodite thioantimonate lithium superionic. Practical challenges and future perspectives of allsolid. This represents the highest conductivity achieved in a solid electrolyte, exceeding even those of liquid organic electrolytes. A firstprinciple investigation of the li diffusion. It exhibits an extremely high lithium ionic conductivity of 12mscm1 at room temperature. Lithium aluminum germanium phosphate lagp is attracting a great deal of attention as a solid electrolyte for lithiumoxygen lio2 batteries due to its high ionic conductivity. Ujjal kumar sur the sustainable production of renewable energy such as solar and wind energy depends on a number of natural condi tions such as duration of the day or night, and velocity and direction of the wind. It exhibits an extremely high lithium ionic conductivity of 12 ms cm1 at room temperature. Here, we report a complex hydride lithium superionic conductor, 0.

This represents the highest conductivity achieved in a solid electrolyte. Membranes in lithium ion batteries semantic scholar. Pdf highpower allsolidstate batteries using sulfide. We also report successful fabrication of a roomtemperature solidstate nas. The excluded regions are due to the vanadium cell used for diffraction measurement. An advanced superionic conductor adsic is fast ion conductor that has a crystal structure close to optimal for fast ion transport fit. Because of the near unity transference number of lithium superionic conductors. Lotschabc one of the key challenges of energy research is finding solid electrolytes with high lithium conductivities comparable to those of liquid electrolytes. Lirich antiperovskite superionic conductors based on. A complex hydride lithium superionic conductor was synthesized by stabilizing the disordered high t phase of a closo type complex hydride containing closo type cagelike complex anions supplementary fig. One key enabler of this discovery is the development of a firstofitskind highthroughput first. The glassceramic conductor primarily consisted of a phase which is the superionic conducting phase.

Diffraction data were obtained using neutron radiation at room temperature. This framework structure has a onedimensional 1d lithium conduction pathway along the c axis. A lithium superionic conductor from first principles. Toyota shows off all solid state lithium superionic. Allsolidstate batteries incorporating lithium metal anode have the potential to address the energy density issues of conventional lithiumion. Experimental 3d lithium diffusion pathway in latp was extracted from the negative nuclear density maps reconstructed by the maximum entropy method. Antiperovskite li3ocl superionic conductor films for solid. Supplementary information a lithium superionic conductor. Us202000671a1 lithium and sodium superionic conductors.

Toyota shows off all solid state lithium superionic conductor based prototype battery. A lithium superionic conductor request pdf researchgate. It exhibits strikingly nonlinear ion exchange properties and may presage the discovery of similar coionic interactions in other superionic conductors. Highthroughput screening of solidstate liion conductors using. Here, we report a lithium superionic conductor, li 10 gep 2 s 12 that has a new threedimensional framework structure. Lithium superionic conductor lisicon li14zngeo44, an important li ion conductor, is a general name for the glassceramic system. Lithium superionic conductors with the li10gep2s12 lgpstype structure are promising materials for use as solid electrolytes in the nextgeneration lithium batteries. Insights into the performance limits of the li p s. Crystal structural framework of lithium superionic conductors. As a stepping stone in the development of new superionic conductors that can be utilized as functinal materials efforts to reevaluate solidinterior diffusion and conduction phenomena of ions and molecules in a superionic conductor on the basis of basic physical properties, and to. Fast lithium ion conduction in lithium phosphidoaluminates.

The new superionic conductor li 10gep 2s 12 has a threedimensional framework structure consisting of ge 0. A glassceramic, lithiumion conductor with a molar composition of 19. Based on some criteria of material design of crystalline ionic conductors figure 6. Due to the negligible grain boundary resistance for sulfide electrolytes, lps exhibits excellent conductivity even under cold pressed conditions. Li ions migrate among the sites through these channels, contributing to overall ionic transport. Lithium superionic conductors with the li10gep2s12 lgpstype structure are promising materials for use as solid electrolytes in the. Since the discovery of lithium superionic conductor li10gep2s12. First principles design of lithium superionic conductors. Lithiumsodium beta alumina having a lithiumsodium ratio greater than about i appears to be the first generally useful lithium superionic conductor that has been reported. The most famous example of advanced superionic conductorsolid electrolyte is rbag 4 i 5 where. These represent the first antimony argyrodites to date. Both candidates are derived from the relatively unexplored quaternary silver thiophosphates.

Influence of lattice polarizability on the ionic conductivity in the lithium superionic argyrodites li 6 ps 5 x x cl, br, i. The final product lagp is obtained by sintering the dry precursor gel at 900 c for. This is a first attempt in which the lithium superionic conductors are designed by the crystal structure prediction method and may help explore. A complex hydride lithium superionic conductor for highenergy. Design principles for solidstate lithium superionic conductors.

Two kinds of stacking sequences of layers of als 2 o 2. Toyota shows off all solid state lithium superionic conductor based prototype battery 26 september 2012, by bob yirka the allsolidstate battery prototype. A solid lithium superionic conductor li11alp2s12 with a thio. A lithium superionic conductor as a new solidstate battery electrolyte. Antiperovskite li 3 ocl superionic conductor films are prepared via pulsed laser deposition using a composite target. In this study, lagp is prepared by a solgel process using comparatively lowcost gecl2 as one of the reactants. A liion conductor material is comprised of a mobile liion sublattice hosted in a crystal structural framework of immobile polyanion groups. Superionic lithium conductor with a cubic argyroditetype. A lithium superionic conductor as a new solidstate battery electrolyte ujjal kumar sur the sustainable production of renewable energy such as solar and wind energy depends on a number of natural conditions such as duration of the day or night, and velocity and direction of the wind. It exhibits an extremely high lithium ionic conductivity of 12 ms cm1 at.

Liion solidstate conductors require high ionic conductivity at room temperature and low activation energy ea for use over a broad range of. Raman scattering study of superionic conductor lithium. Here, we report a lithium superionic conductor, li10gep2s12 that has a new threedimensional framework structure. Pdf design principles for solidstate lithium superionic conductors. A complex hydride lithium superionic conductor for high. Superionic conductors are highly promising functional materials. New lithium superionic conductors predicted from silver.

Impedance characterization reveals mixed conducting. However, supply of such renewable energies is noncontinous. Datadriven discovery and design of superionic lithium conductors for high performance lithium ion batteries 26 techniques to build ionic conductivity predictors, thus facilitating timeef. Here, we show that clusterbased lithium superionic conductors can have very high conductivities of 10. Vajeeston department of chemistry, centre for materials science and nanotechnology, university of oslo, norway, box 1033 blindern, n0315 oslo, norway. We report on the novel superionic conductor li9alp4 which is easily synthesised from the elements via ballmilling and subsequent annealing at moderate temperatures and. High power allsolidstate batteries using sulphide superionic conductors yuki kato1,2,3 satoshi hori,2 toshiya saito,1 kota suzuki,2 masaaki hirayama,2 akio mitsui4, masao yonemura5, hideki iba1, and ryoji kanno2 1battery research div.